Share to: share facebook share twitter share wa share telegram print page

 

Transposed Paternò−Büchi reaction

The transposed Paternò−Büchi reaction involves a ππ* excited state of alkene reacting with a ground state carbonyl functionality. This is reversal of the traditional Paternò−Büchi reaction where an excited carbonyl group reacts with a ground state alkene. This strategy was first reported by Sivaguru and co-workers with reaction of enamides.[1]

References

  1. ^ Kumarasamy, Elango; Raghunathan, Ramya; Kandappa, Sunil Kumar; Sreenithya, A.; Jockusch, Steffen; Sunoj, Raghavan B; Sivaguru, J. (2017-01-18). "Transposed Paternò–Büchi Reaction". Journal of the American Chemical Society. 139 (2): 655–662. doi:10.1021/jacs.6b05936. ISSN 0002-7863. PMID 27958726.
Prefix: a b c d e f g h i j k l m n o p q r s t u v w x y z 0 1 2 3 4 5 6 7 8 9

Portal di Ensiklopedia Dunia

Kembali kehalaman sebelumnya